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Journal Article

S=2 Spin Ladders in the Sulfide Oxide BaFe2S2O

MPS-Authors
http://pubman.mpdl.mpg.de/cone/persons/resource/persons126889

Valldor,  Martin
Martin Valldor, Physics of Correlated Matter, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons126506

Adler,  Peter
Peter Adler, Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons126806

Prots,  Yurii
Yuri Prots, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons126556

Burkhardt,  Ulrich
Ulrich Burkhardt, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons126881

Tjeng,  Liu Hao
Liu Hao Tjeng, Physics of Correlated Matter, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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Citation

Valldor, M., Adler, P., Prots, Y., Burkhardt, U., & Tjeng, L. H. (2014). S=2 Spin Ladders in the Sulfide Oxide BaFe2S2O. European Journal of Inorganic Chemistry, (36), 6150-6155. doi:10.1002/ejic.201402805.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0024-BFC3-D
Abstract
Pure powder and small single crystals of BaFe2S2O were obtained by solid-state reaction between BaO, Fe, and S in closed silica ampoules. The crystal structure contains a magnetic ladderlike sublattice of high-spin Fe2+ (d(6)) tetrahedrally coordinated by three S and one O atoms. Strong antiferromagnetic spin interactions are observed far above the Neel transition (T-N = 260 K). Fe-57 Mossbauer spectra show typical features of Fe2+ as a doublet with large quadrupole splitting above T-N and combined electric and magnetic hyperfine interaction in the magnetically ordered phase. A structural transition upon the magnetic order is discussed.