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Journal Article

Coordination Chemistry of Ene-1,1-diamines and a Prototype "Carbodicarbene"

MPS-Authors
http://pubman.mpdl.mpg.de/cone/persons/resource/persons58380

Fürstner,  Alois
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons58392

Alcarazo,  Manuel
Research Group Alcarazo, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons58578

Goddard,  Richard
Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons58744

Lehmann,  Christian W.
Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Supplementary Material (public)

z705798_s.pdf
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Citation

Fürstner, A., Alcarazo, M., Goddard, R., & Lehmann, C. W. (2008). Coordination Chemistry of Ene-1,1-diamines and a Prototype "Carbodicarbene". Angewandte Chemie International Edition, 47(17), 3210-3214. doi:10.1002/anie.200705798.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0024-C2C4-3
Abstract
Carbophilic Lewis acids can polarize a coordinated π-bond by a slippage mechanism. A series of stable ylid- or enolate gold complexes of ene-1,1-diamines not only emulate this property, but also reveal the exceptional donor capacity of such electron-rich olefin ligands. Moreover, the first metal complex of a tetraaminoallene is reported, which features a prototype “carbodicarbene” ligand bound to a transition-metal template.