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Nickel(I)-Komplexe mit 1,1′-Bis(phosphino)ferrocenen als Liganden

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http://pubman.mpdl.mpg.de/cone/persons/resource/persons59042

Theyssen,  Nils
Institut für Anorganische und Analytische Chemie der Universität Jena, Lessingstraße 8, D-07743 Jena, Fax: (+49) (0)3641 948102;
Service Department Theyssen (Technical Labs), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Langer, J., Fischer, R., Görls, H., Theyssen, N., & Walther, D. (2007). Nickel(I)-Komplexe mit 1,1′-Bis(phosphino)ferrocenen als Liganden. Zeitschrift für anorganische und allgemeine Chemie, 633(4), 557-562. doi:10.1002/zaac.200600350.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0024-52D4-B
Abstract
Nickel(I) Complexes with 1,1′-Bis(phosphino)ferrocenes as Ligands. The thermically stable monomeric Nickel(I) complexes [(dtbpf)Ni(acac)] (1) and [(dippf)NiCl] (2) were synthesized and characterized by elemental analyses, EPR spectroscopy, and by X-ray crystal structure analyses of single crystals (dtbpf: 1,1′-bis(di-tertbutylphosphino)ferrocene; dippf: 1,1′-bis(diisopropylphosphino)ferrocene). 1 is formed by reduction of Ni(acac)2 with triethylaluminium in the presence of dtbpf, together with the nickel(0) complex [(dtbpf)Ni(C2H4)]. 1 contains a NiI atom surrounded of two O- and two P donor atoms in a distorted tetrahedral coordination. 2 was obtained by reduction of [(dippf)NiCl2] with NaBH4. In 2 the nickel(I) atom adopts trigonal planar coordination.