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Concise total syntheses of epothilone A and C based on alkyne metathesis

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Fürstner,  Alois
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Mathes,  Christian
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

Grela,  Karol
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Fürstner, A., Mathes, C., & Grela, K. (2001). Concise total syntheses of epothilone A and C based on alkyne metathesis. Chemical Communications, (12), 1057-1059. doi:10.1039/B101669P.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0024-3952-8
Abstract
A ring closing alkyne metathesis reaction catalyzed by the molybdenum complex 26 followed by a Lindlar reduction of the resulting cycloalkyne product opens an efficient and stereoselective entry into epothilone A and C.