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Journal Article

Theoretical study of electronic relaxation processes in hydrated Gd3+ complexes in solutions

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Citation

Rast, S., Fries, P., & Belorizky, E. (1999). Theoretical study of electronic relaxation processes in hydrated Gd3+ complexes in solutions. Journal de Chimie Physique et de Physico-Chimie Biologique, 96, 1543-1550. doi:10.1051/jcp:1999231.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0023-D9FD-0
Abstract
The EPR line widths of [Gd(H2O)(8)](3+) measured in water at various magnetic fields by Merbach's group have been reinterpreted. A theoretical model of the transverse electronic relaxation is proposed, All the terms of the static zero-field splitting (ZFS) allowed by the symmetry of the complex are included and shown to have a significant contribution. The influence of a transient distortion ZFS is also studied.