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Deuterium NMR of pyridine intercalated cadmium chalcogenophosphate

MPG-Autoren
http://pubman.mpdl.mpg.de/cone/persons/resource/persons128263

Zimmermann,  Herbert
Department of Molecular Physics, Max Planck Institute for Medical Research, Max Planck Society;
Department of Biomolecular Mechanisms, Max Planck Institute for Medical Research, Max Planck Society;
Zimmermann Group, Max Planck Institute for Medical Research, Max Planck Society;
Emeritus Group Biophysics, Max Planck Institute for Medical Research, Max Planck Society;

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Zitation

Lishitz, E., Vega, S., Luz, Z., Francis, A. H., & Zimmermann, H. (1986). Deuterium NMR of pyridine intercalated cadmium chalcogenophosphate. Journal of Physics and Chemistry of Solids, 47(11), 1045-1048. doi:10.1016/0022-3697(86)90070-3.


Zitierlink: http://hdl.handle.net/11858/00-001M-0000-0019-AED5-F
Zusammenfassung
Deuterium NMR spectra of the intercalation complexes of lamellar Cd2P2S6 with various deuterated pyridine molecules are reported. The measurements indicate that the pyridine molecules lie within the chalcogen van der Waals gaps with their molecular planes parallel to the chalcogen layers. Between room temperature and −60°C the pyridine molecules reorient rapidly (on the NMR time scale) about an axis perpendicular to their molecular plane.