Ternary Rare-Earth Transition-Metal Polyhydride Cluster Compounds

Bauer, Tobias; Wagner, Frank R.; Kempe, Rhett

doi:10.1002/chem.201301290

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Ternary Rare-Earth Transition-Metal Polyhydride Cluster Compounds

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Wagner, Frank R.
Frank Wagner, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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Citation

Bauer, T., Wagner, F. R., & Kempe, R. (2013). Ternary Rare-Earth Transition-Metal Polyhydride Cluster Compounds. Chemistry - A European Journal, 19(27), 8732-8735. doi:10.1002/chem.201301290.

Cite as: https://hdl.handle.net/11858/00-001M-0000-0018-09A0-3

Abstract

Combining three: The first examples of ternary rare-earth transition-metal polyhydride clusters (see figure) are reported. Cluster formation proceeds through C[BOND]H bond activation of the Cp ligands that stabilize the transition-metal-containing starting material. Analysis of the electronic structure of the polyhydride cluster compounds revealed covalent Re[BOND]Lu bonding and ionic transition metal hydride–Lu interactions.