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Ternary Rare-Earth Transition-Metal Polyhydride Cluster Compounds

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http://pubman.mpdl.mpg.de/cone/persons/resource/persons126896

Wagner,  Frank R.
Frank Wagner, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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Citation

Bauer, T., Wagner, F. R., & Kempe, R. (2013). Ternary Rare-Earth Transition-Metal Polyhydride Cluster Compounds. Chemistry - A European Journal, 19(27), 8732-8735. doi:10.1002/chem.201301290.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0018-09A0-3
Abstract
Combining three: The first examples of ternary rare-earth transition-metal polyhydride clusters (see figure) are reported. Cluster formation proceeds through C[BOND]H bond activation of the Cp ligands that stabilize the transition-metal-containing starting material. Analysis of the electronic structure of the polyhydride cluster compounds revealed covalent Re[BOND]Lu bonding and ionic transition metal hydride–Lu interactions.