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On the Binary Compound YbGa5

MPS-Authors
http://pubman.mpdl.mpg.de/cone/persons/resource/persons126616

Giedigkeit,  R.
Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons126783

Niewa,  R.
Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons126838

Schnelle,  W.
Walter Schnelle, Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons126626

Grin,  Y.
Juri Grin, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons126692

Kniep,  R.
Rüdiger Kniep, Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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Citation

Giedigkeit, R., Niewa, R., Schnelle, W., Grin, Y., & Kniep, R. (2002). On the Binary Compound YbGa5. Zeitschrift für Anorganische und Allgemeine Chemie, 628(7), 1692-1696. doi:10.1002/1521-3749(200207)628:7<1692:AID-ZAAC1692>3.0.CO;2-Y.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0015-3139-8
Abstract
YbGa5 was characterized in course of a re-investigation of the Yb-Ga system in the range between 0 and 20 at. % Yb. The compound can be described as a defect variant of the Ce2Ga10Ni structure type (space group 14/mmm, a = 430.59(4) pm, c = 2587.1(4) pm). The special feature of the crystal structure is given by local disorder within the gallium network. From magnetic susceptibility, ytterbium is in the valence state 2+.