English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
Add to Basket
  Local TagsRelease HistoryDetailsSummary

Released
Journal Article

An Atom-Economical and Stereoselective Domino Synthesis of Functionalised Dienes

MPS-Authors
/persons/resource/persons59007

Souris,  Caroline
Research Group Maulide, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons58783

Luparia,  Marco
Research Group Maulide, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons58553

Frébault,  Frédéric
Research Group Maulide, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons58402

Audisio,  Davide
Research Group Maulide, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons58537

Farès,  Christophe
Service Department Farès (NMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons58578

Goddard,  Richard
Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons58809

Maulide,  Nuno
Research Group Maulide, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

External Resource
No external resources are shared
Fulltext (restricted access)
There are currently no full texts shared for your IP range.
Fulltext (public)
There are no public fulltexts stored in PuRe
Supplementary Material (public)

chem_201300776_sm_miscellaneous_information.pdf
(Supplementary material), 8MB

Citation

Souris, C., Luparia, M., Frébault, F., Audisio, D., Farès, C., Goddard, R., et al. (2013). An Atom-Economical and Stereoselective Domino Synthesis of Functionalised Dienes. Chemistry – A European Journal, 19(21), 6566-6570. doi:10.1002/chem.201300776.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0014-CA09-1
Abstract
Open sesame: A direct synthesis of functionalised and stereodefined dienes, relying on a domino allylic alkylation/electrocyclic ring-opening sequence, is reported. This method allows concise access to doubly vinylogous esters. A further systematic study of ring-opening rates of carbon-substituted cyclobutenes allowed the design of substrates amenable to sequential pericyclic reactions.