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Journal Article

Total Synthesis of Tulearin C

MPS-Authors
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Lehr,  Konrad
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Mariz,  Ronaldo
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Leseurre,  Lucie
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Gabor,  Barbara
Service Department Farès (NMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Fürstner,  Alois
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Supplementary Material (public)

anie_201106117_sm_miscellaneous_information.pdf
(Supplementary material), 7MB

Citation

Lehr, K., Mariz, R., Leseurre, L., Gabor, B., & Fürstner, A. (2011). Total Synthesis of Tulearin C. Angewandte Chemie International Edition, 50(48), 11373-11377. doi:10.1002/anie.201106117.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0014-CA21-7
Abstract
With the help of the smaller brother: Although alkyne metathesis will always be the little brother of alkene metathesis, it allows problems to be solved that are currently beyond reach of the more famous sibling. This notion is exemplified by the tulearin macrolides, which could only be selectively forged by ring-closing alkyne metathesis (RCAM)/trans reduction using the latest generation of alkyne metathesis catalysts.