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Journal Article

The Leiodolide B Puzzle

MPS-Authors
http://pubman.mpdl.mpg.de/cone/persons/resource/persons132974

Larivée,  Alexandre
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons59062

Unger,  John B.
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons59046

Thomas,  Mickael
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons59119

Wirtz,  Cornelia
Service Department Farès (NMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons132976

Dubost,  Christophe
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons58601

Handa,  Shinya
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons58380

Fürstner,  Alois
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Supplementary Material (public)

anie_201005850_sm_miscellaneous_information.pdf
(Supplementary material), 306KB

Citation

Larivée, A., Unger, J. B., Thomas, M., Wirtz, C., Dubost, C., Handa, S., et al. (2011). The Leiodolide B Puzzle. Angewandte Chemie International Edition, 50(1), 304-309. doi:10.1002/anie.201005850.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0014-CA27-C
Abstract
Out of options? Even though a systematic approach was chosen, which led to a set of four diastereomeric macrolides modeled around the proposed structure of leiodolide B (see picture), the puzzle concerning the stereostructure of this cytotoxic metabolite derived from a deep-sea sponge still remains unsolved.