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Journal Article

Sulfoxide-mediated Umpolung of alkali halide salts

MPS-Authors
http://pubman.mpdl.mpg.de/cone/persons/resource/persons58701

Klimczyk,  Sebastian
Research Group Maulide, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons58636

Huang,  Xueliang
Research Group Maulide, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons58537

Farès,  Christophe
Service Department Farès (NMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons58809

Maulide,  Nuno
Research Group Maulide, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Supplementary Material (public)

c2ob25459j.pdf
(Supplementary material), 878KB

Citation

Klimczyk, S., Huang, X., Farès, C., & Maulide, N. (2012). Sulfoxide-mediated Umpolung of alkali halide salts. Organic & Biomolecular Chemistry, 10(22), 4327-4329. doi:10.1039/C2OB25459J.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0014-CA2F-B
Abstract
A new protocol for the direct two-electron oxidative Umpolung of alkali halide salts is reported. This procedure, relying on the use of a commercially available sulfoxide as the oxidant, allows the electrophilic halogenation of carbonyl compounds as well as halolactonisation reactions to proceed from the corresponding sodium salts, at room temperature and under mild conditions.