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Journal Article

Carbon Dioxide as a C1 Building Block for the Formation of Carboxylic Acids by Formal Catalytic Hydrocarboxylation

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Leitner,  Walter
Institut für Technische und Makromolekulare Chemie RWTH Aachen University;
Service Department Leitner (Technical Labs), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Ostapowicz, T. G., Schmitz, M., Krystof, M., Klankermayer, J., & Leitner, W. (2013). Carbon Dioxide as a C1 Building Block for the Formation of Carboxylic Acids by Formal Catalytic Hydrocarboxylation. Angewandte Chemie International Edition, 52(46), 12119-12123. doi:10.1002/anie.201304529.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0014-C9E3-E
Abstract
A happy marriage of two processes: An effective catalytic system was identified for the direct synthesis of carboxylic acids from non-activated olefins or alcohols, CO2, and H2. Detailed analysis together with labeling studies indicated that the overall hydrocarboxylation of simple olefins results from a combination of the reverse water–gas shift (rWGS) reaction and a hydroxycarbonylation step, each promoted by a rhodium catalyst.