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Journal Article

Facile insertion of CO2 into metal–phenoxide bonds

MPS-Authors
http://pubman.mpdl.mpg.de/cone/persons/resource/persons58749

Leitner,  Walter
Institut für technische und makromolekulare Chemie, RWTH Aachen University;
Service Department Leitner (Technical Labs), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Supplementary Material (public)

c3gc40147b.pdf
(Supplementary material), 579KB

Citation

Elmas, S., Subhani, M. A., Vogt, H., Leitner, W., & Müller, T. E. (2013). Facile insertion of CO2 into metal–phenoxide bonds. Green Chemistry, 15(5), 1356-1360. doi:10.1039/C3GC40147B.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0014-A38B-8
Abstract
The activation of CO2 is highlighted for two lead-structures of cobalt- and zinc-based homogeneous catalysts used in the copolymerization of epoxides and CO2. Following the activation of CO2 with in situ ATR-IR spectroscopy, a surprisingly facile insertion of CO2 into metal–phenoxide bonds was revealed.