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Journal Article

Methyl formate as a carbonylating agent for the catalytic conversion of phenol to methyl phenyl carbonate

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Leitner,  Walter
Lehrstuhl für Technische Chemie und Petrolchemie, Institut für Technische und Makromolekulare Chemie, RWTH Aachen University;
Service Department Leitner (Technical Labs), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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c3gc36877g.pdf
(Supplementary material), 361KB

Citation

Yalfani, M. S., Lolli, G., Wolf, A., Mleczko, L., Müller, T. E., & Leitner, W. (2013). Methyl formate as a carbonylating agent for the catalytic conversion of phenol to methyl phenyl carbonate. Green Chemistry, 15(5), 1146-1149. doi:10.1039/c3gc36877g.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0014-A280-8
Abstract
Methyl formate was used as a green and efficient carbonylating agent in the synthesis of methyl phenyl carbonate from phenol. Methyl formate showed better performance compared to toxic CO gas and the ability to produce other useful carbonylated products, e.g., dimethyl carbonate and dimethyl oxalate.