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Journal Article

Trimethylenemethane-Ruthenium(II)-Triphos complexes as highly active catalysts for catalytic C—O bond cleavage reactions of lignin model compounds

MPS-Authors
http://pubman.mpdl.mpg.de/cone/persons/resource/persons58749

Leitner,  Walter
Institut für Technische und Makromolekulare Chemie, RWTH Aachen University;
Service Department Leitner (Technical Labs), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Supplementary Material (public)

cctc_201200215_sm_miscellaneous_information.pdf
(Supplementary material), 182KB

Citation

vom Stein, T., Weigang, T., Merkens, C., Klankermayer, J., & Leitner, W. (2013). Trimethylenemethane-Ruthenium(II)-Triphos complexes as highly active catalysts for catalytic C—O bond cleavage reactions of lignin model compounds. ChemCatChem, 5(2), 439-441. doi:10.1002/cctc.201200215.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0014-A29E-8
Abstract
Ru ready for it yet? The reaction of [Ru(cod)(methallyl)2] with tripodal phosphine ligands of the TRIPHOS-type results in the formation of Ru-trimethylenemethane complexes. Evaluation of their catalytic properties revealed a high activity for hydrogen transfer and C—O cleavage reactions including the hydrogen-free reductive cleavage of 2-aryloxy-1-arylethanols as model compounds for lignin linkages.