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Journal Article

Synthesis of 1-Octanol and 1,1-Dioctyl Ether from Biomass-Derived Platform Chemicals

MPS-Authors
http://pubman.mpdl.mpg.de/cone/persons/resource/persons58749

Leitner,  Walter
Institut für Technische und Makromolekulare Chemie, RWTH Aachen University;
Service Department Leitner (Technical Labs), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Supplementary Material (public)

anie_201203669_sm_miscellaneous_information.pdf
(Supplementary material), 2MB

Citation

Julis, J., & Leitner, W. (2012). Synthesis of 1-Octanol and 1,1-Dioctyl Ether from Biomass-Derived Platform Chemicals. Angewandte Chemie International Edition: a journal of the Gesellschaft Deutscher Chemiker, 51(34), 8615-8619. doi:10.1002/anie.201203669.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0014-A299-1
Abstract
The happy medium: A new catalytic pathway for the synthesis of the linear primary C8 alcohol products 1-octanol and dioctyl ether from furfural and acetone has been developed using retrosynthetic analysis. This opens a general strategy for the synthesis of medium-chain-length alcohols from carbohydrate feedstock.