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Journal Article

Continuous-Flow Hydrogenation of Carbon Dioxide to Pure Formic Acid using an Integrated scCO2 Process with Immobilized Catalyst and Base

MPS-Authors

Wesselbaum,  Sebastian
Institut für Technische Chemie, RWT Aachen University;
Research Group of Nanoscale Spin Imaging, MPI for Biophysical Chemistry, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons58749

Leitner,  Walter
Institut für Technische Chemie, RWT Aachen University;
Service Department Leitner (Technical Labs), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Supplementary Material (public)

anie_201203185_sm_miscellaneous_information.pdf
(Supplementary material), 2MB

Citation

Wesselbaum, S., Hintermair, U., & Leitner, W. (2012). Continuous-Flow Hydrogenation of Carbon Dioxide to Pure Formic Acid using an Integrated scCO2 Process with Immobilized Catalyst and Base. Angewandte Chemie International Edition: a journal of the Gesellschaft Deutscher Chemiker, 51(34), 8585-8588. doi:10.1002/anie.201203185.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0014-A2AA-A
Abstract
Dual role for CO2: Pure formic acid can be obtained continuously by hydrogenation of CO2 in a single processing unit (see scheme). An immobilized ruthenium organometallic catalyst and a nonvolatile base in an ionic liquid (IL) are combined with supercritical CO2 as both reactant and extractive phase.