de.mpg.escidoc.pubman.appbase.FacesBean
English
 
Help Guide Disclaimer Contact us Login
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT

Released

Journal Article

Hydrogenation of Carbon Dioxide to Methanol by Using a Homogeneous Ruthenium–Phosphine Catalyst

MPS-Authors
http://pubman.mpdl.mpg.de/cone/persons/resource/persons58749

Leitner,  Walter
Institut für Technische und Makromolekulare Chemie, RWTH Aachen University;
Service Department Leitner (Technical Labs), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

Locator
There are no locators available
Fulltext (public)
There are no public fulltexts available
Supplementary Material (public)

anie_201202320_sm_miscellaneous_information.pdf
(Supplementary material), 354KB

Citation

Wesselbaum, S., vom Stein, T., Klankermayer, J., & Leitner, W. (2012). Hydrogenation of Carbon Dioxide to Methanol by Using a Homogeneous Ruthenium–Phosphine Catalyst. Angewandte Chemie International Edition: a journal of the Gesellschaft Deutscher Chemiker, 51(30), 7499-7502. doi:10.1002/anie.201202320.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0014-A2C0-5
Abstract
Simply efficient: The homogenously catalyzed hydrogenation of CO2 to methanol is achieved by using a ruthenium phosphine complex under relatively mild conditions (see scheme; HNTf2=bis(trifluoromethane)sulfonimide). This is the first example of CO2 hydrogenation to methanol by using a single molecularly defined catalyst.