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Journal Article

SYNTHESIS OF GLYCOSIDES OF FUCOSE UNDER NEUTRAL CONDITIONS IN SOLUTIONS OF LICLO4 IN ORGANIC-SOLVENTS

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http://pubman.mpdl.mpg.de/cone/persons/resource/persons98735

Waldmann,  Herbert
Abt. IV: Chemische Biologie, Max Planck Institute of Molecular Physiology, Max Planck Society;

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Citation

BOHM, G., & Waldmann, H. (1995). SYNTHESIS OF GLYCOSIDES OF FUCOSE UNDER NEUTRAL CONDITIONS IN SOLUTIONS OF LICLO4 IN ORGANIC-SOLVENTS. TETRAHEDRON LETTERS, 36(22), 3843-3846. doi:10.1016/0040-4039(95)00637-R.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0014-9CBF-7
Abstract
The glycosyl donors 2,3,4-tri-0-benzyl fucosyl fluoride and -trichloroacetimidate are activated under neutral conditions in 1M solutions of LiClO4 in CH2Cl2 or ether to react with mono- and disaccharides to give fucosyl glycosides in high yields and with high stereoselectivity.