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Adapting a Wacker-type catalyst system to the palladium-catalyzed oxidative carbonylation of aliphatic polyols

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http://pubman.mpdl.mpg.de/cone/persons/resource/persons58749

Leitner,  Walter
Service Department Leitner (Technical Labs), Max-Planck-Institut für Kohlenforschung, Max Planck Society;
Institut für Technische und Makromolekulare Chemie, Technische Chemie und Petrolchemie, RWTH Aachen University;

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Citation

Doro, F., Winnertz, P., Leitner, W., Prokofieva, A., & Müller, T. E. (2011). Adapting a Wacker-type catalyst system to the palladium-catalyzed oxidative carbonylation of aliphatic polyols. Green Chemistry, 13(2), 292-295. doi:10.1039/C0GC00817F.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0014-A318-C
Abstract
Polyols, which can be obtained readily from bio-feedstock, are converted efficiently into their corresponding cyclic carbonates by using a Wacker-type Pd/Mn catalyst system. A fine tuned redox cascade is essential in ensuring a high productivity of the Pd catalyst in the oxidative carbonylation reaction. Turnover numbers up to 784 molproduct/molpalladium were achieved.