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Journal Article

Synthesis and Reactivity of Metal Complexes with Acyclic (Amino)(Ylide)Carbene Ligands

MPS-Authors
http://pubman.mpdl.mpg.de/cone/persons/resource/persons104638

González-Fernández,  Elisa
Research Group Alcarazo, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons58946

Rust,  Jörg
Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons58392

Alcarazo,  Manuel
Research Group Alcarazo, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Supplementary Material (public)

anie_201305311_sm_miscellaneous_information.pdf
(Supplementary material), 4MB

Citation

González-Fernández, E., Rust, J., & Alcarazo, M. (2013). Synthesis and Reactivity of Metal Complexes with Acyclic (Amino)(Ylide)Carbene Ligands. Angewandte Chemie International Edition: a journal of the Gesellschaft Deutscher Chemiker, 52(43), 11392-11395. doi:10.1002/anie.201305311.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0014-A31C-4
Abstract
No cycle required: The straightforward synthesis of acyclic (amino)(ylide)carbene gold complexes was achieved by reaction of isocyanide gold complexes with phosphorus and arsenic ylides as well as electron-rich olefins. Their ability to form bimetallic species and to act as ligand-transfer reagents has also been established.