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AMINO-ACID ESTERS - VERSATILE CHIRAL AUXILIARY GROUPS FOR THE ASYMMETRIC-SYNTHESIS OF NITROGEN-HETEROCYCLES

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http://pubman.mpdl.mpg.de/cone/persons/resource/persons98735

Waldmann,  Herbert
Abt. IV: Chemische Biologie, Max Planck Institute of Molecular Physiology, Max Planck Society;

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Waldmann, H. (1995). AMINO-ACID ESTERS - VERSATILE CHIRAL AUXILIARY GROUPS FOR THE ASYMMETRIC-SYNTHESIS OF NITROGEN-HETEROCYCLES. SYNLETT, (2), 133-141.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0014-729E-1
Abstract
The development of amino acid esters as chiral auxiliary groups for the asymmetric construction of N-heterocycles by means of aza Diels-Alder reactions, Mannich reactions, Pictet-Spengler reactions and 1,3-dipolar cycloadditions is described. Also their application in the steric steering of carbo Diels-Alder reactions, radicalic transformations and enantioselective nucleophilic additions to carbonyl groups is highlighted.