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An enzyme-initiated domino hydroxylation-oxidation carbo Diels-Alder reaction cascade

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http://pubman.mpdl.mpg.de/cone/persons/resource/persons98735

Waldmann,  Herbert
Abt. IV: Chemische Biologie, Max Planck Institute of Molecular Physiology, Max Planck Society;

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Muller, G., & Waldmann, H. (1996). An enzyme-initiated domino hydroxylation-oxidation carbo Diels-Alder reaction cascade. TETRAHEDRON LETTERS, 37(22), 3833-3836. doi:10.1016/0040-4039(96)00727-7.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0014-71F9-E
Abstract
In a domino hydroxylation-oxidation-Diels-Alder reaction sequence which is initiated by the enzyme tyrosinase simple phenols ate converted in high yield into highly functionalized bicyclic 1,2-diketones. This example demonstrates that enzymatic transformations can successfully be combined with nonenzymatic reactions in domino reaction sequences. Copyright (C) 1996 Elsevier Science Ltd