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The Redox-Neutral Approach to C-H Functionalization

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http://pubman.mpdl.mpg.de/cone/persons/resource/persons58879

Peng,  Bo
Research Group Maulide, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons58809

Maulide,  Nuno
Research Group Maulide, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Peng, B., & Maulide, N. (2013). The Redox-Neutral Approach to C-H Functionalization. Chemistry-a European Journal, 19(40), 13274-13287. doi:10.1002/chem.201301522.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0014-A397-C
Abstract
The direct functionalization of C[BOND]H bonds is an attractive strategy in organic synthesis. Although several advances have been made in this area, the selective activation of inert sp3 C[BOND]H bonds remains a daunting challenge. Recently, a new type of sp3 C[BOND]H activation mode through internal hydride transfer has demonstrated the potential to activate remote sp3 C[BOND]H linkages in an atom-economic manner. This Minireview attempts to classify recent advances in this area including the transition to non-activated sp3 C[BOND]H bonds and asymmetric hydride transfers.