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Synthesis, structure and reactivity of cyclopropenyl-1-ylidene stabilized S(II), Se(II) and Te(II) mono- and dications

MPS-Authors
http://pubman.mpdl.mpg.de/cone/persons/resource/persons101536

Kozma,  Ágnes
Research Group Alcarazo, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons58884

Petuškova,  Jekaterina
Research Group Alcarazo, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons58744

Lehmann,  Christian W.
Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons58392

Alcarazo,  Manuel
Research Group Alcarazo, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Supplementary Material (public)

c2cc36225b-1.pdf
(Supplementary material), 2MB

c2cc36225b.txt
(Supplementary material), 372KB

Citation

Kozma, Á., Petuškova, J., Lehmann, C. W., & Alcarazo, M. (2013). Synthesis, structure and reactivity of cyclopropenyl-1-ylidene stabilized S(II), Se(II) and Te(II) mono- and dications. Chemical Communications, 49, 4145-4147. doi:10.1039/C2CC36225B.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0014-A3E7-7
Abstract
The syntheses and structural characterization of carbene-stabilized chalcogen centred mono- and dications employing a reverse electron demand onio-substitutent transfer strategy are reported. The electronic structures of these compounds were determined by density functional calculations and their reactivity towards Pd(0) centres was evaluated.