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Synthesis and Structure of Carbene-Stabilized N-Centered Cations [L2N]+, [L2NR]2+, [LNR3]2+, and [L3N]3+

MPS-Authors
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Kozma,  Ágnes
Research Group Alcarazo, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Gopakumar,  Gopinadhanpillai
Research Department Thiel, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Farès,  Christophe
Service Department Farès (NMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Thiel,  Walter
Research Department Thiel, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Alcarazo,  Manuel
Research Group Alcarazo, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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chem_201204186_sm_miscellaneous_information.pdf
(Supplementary material), 3MB

Citation

Kozma, Á., Gopakumar, G., Farès, C., Thiel, W., & Alcarazo, M. (2013). Synthesis and Structure of Carbene-Stabilized N-Centered Cations [L2N]+, [L2NR]2+, [LNR3]2+, and [L3N]3+. Chemistry – A European Journal, 19(11), 3542-3546. doi:10.1002/chem.201204186.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0014-A3F5-7
Abstract
Crystallized! Mono-, di-, and tricationic amines that display unprecedented chemical environments around the central nitrogen atom have been structurally characterized. Cyclic voltammetry experiments and density functional calculations have been performed to gain insight into the electronic structure of these new compounds.