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Journal Article

Catalytic Asymmetric Three-Component Synthesis of Homoallylic Amines

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Gandhi,  Shikha
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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List,  Benjamin
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Gandhi, S., & List, B. (2013). Catalytic Asymmetric Three-Component Synthesis of Homoallylic Amines. Angewandte Chemie International Edition, 52(9), 2573-2576. doi:10.1002/anie.201209776.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0014-A447-9
Abstract
It takes three to make things go right: The first direct asymmetric three‐component reaction of aldehydes, carbamates, and allyltrimethylsilane leading to enantioenriched homoallylic amines has been developed using a new chiral disulfonimide catalyst (see scheme). The method employs readily available, inexpensive, and nontoxic starting materials and is applicable to both aromatic and aliphatic aldehydes.