The Catalytic Asymmetric Acetalization

Kim, Ji Hye; Čorić, Ilija; Vellalath, Sreekumar; List, Benjamin

doi:10.1002/anie.201300120

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The Catalytic Asymmetric Acetalization

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Kim, Ji Hye
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Čorić, Ilija
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Vellalath, Sreekumar
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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List, Benjamin
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Kim, J. H., Čorić, I., Vellalath, S., & List, B. (2013). The Catalytic Asymmetric Acetalization. Angewandte Chemie International Edition, 52(16), 4474-4477. doi:10.1002/anie.201300120.

Cite as: https://hdl.handle.net/11858/00-001M-0000-0014-A450-4

Abstract

In straitened circumstances: In an asymmetric version of the acid‐catalyzed acetalization of aldehydes, a novel member of the chiral confined Brønsted acid family significantly outperformed previously established catalysts, providing cyclic acetals with excellent enantioselectivity (see scheme; Ar=2‐iPr‐5‐MeC₆H₃).