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Journal Article

Higher Alcohol Synthesis: Product Analysis using the Concept of Effective Carbon Numbers

MPS-Authors
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Frank,  Benjamin
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

/persons/resource/persons49294

Xie,  Zailai
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

/persons/resource/persons22181

Trunschke,  Annette
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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ChemIngTechn.pdf
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Citation

Frank, B., Xie, Z., & Trunschke, A. (2013). Higher Alcohol Synthesis: Product Analysis using the Concept of Effective Carbon Numbers. Chemie-Ingenieur-Technik, 85(8), 1290-1293. doi:10.1002/cite.201300006.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0014-1881-C
Abstract
A catalytic set-up for Fischer-Tropsch synthesis to alkanes and alcohols is described. Within
this single-channel reactor unit the reaction conditions can be varied in the ranges of 25-
400°C, 1-100 bar, and 300-120,000 h-1 (GHSV). The broad product spectrum is efficiently
analyzed by GC/MS. The concept of effective carbon numbers, as typically applied in refining
and high-molecular chemistry, is suitable for the product spectrum comprising mainly alkanes,
alkenes, alcohols, aldehydes, and carboxylic acids. This article provides details about the setup
and general measurement procedures.