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Thermokinetic study of the reduction process of a CuO/ZnAl2O4 catalyst

MPG-Autoren
http://pubman.mpdl.mpg.de/cone/persons/resource/persons32715

Tarasov,  Andrey
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons21771

Kühl,  Stefanie
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons85194

Schumann,  Julia
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons21347

Behrens,  Malte
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Zitation

Tarasov, A., Kühl, S., Schumann, J., & Behrens, M. (2013). Thermokinetic study of the reduction process of a CuO/ZnAl2O4 catalyst. High Temperatures-High Pressures: The International Journal of Thermophysical Properties Research, 42(4), 377-386. Retrieved from http://www.oldcitypublishing.com/HTHP/HTHPcontents/HTHP42.4contents.html.


Zitierlink: http://hdl.handle.net/11858/00-001M-0000-0013-FAEB-8
Zusammenfassung
Formal kinetic analysis of reduction process of the Cu-based layered double hydroxide – LDH catalyst precursor for methanol synthesys was implemented. The process was studied by means of thermogravimetry (TG) and Differential scanning calorimetry (DSC) with respect to changes taking place in gas phase, which was analyzed by Massspectrometry (MS). The kinetic parameters of the non-isothermal reduction were determined and the rate limiting step was found.