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Silica-Supported TEMPO Catalysts: Synthesis ad Application in the Anelli Oxidation of Alcohols

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http://pubman.mpdl.mpg.de/cone/persons/resource/persons84817

Fischer,  HH
Max Planck Institute for Biological Cybernetics, Max Planck Society;

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Fey, T., Fischer, H., Bachmann S, Albert, K., & Bolm, C. (2001). Silica-Supported TEMPO Catalysts: Synthesis ad Application in the Anelli Oxidation of Alcohols. Journal of Organic Chemistry, 66(24), 8154-8159. Retrieved from http://pubs.acs.org/cgi-bin/article.cgi/joceah/2001/66/i24/pdf/jo010535q.pdf.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0013-E348-9
Abstract
The application of silica-supported TEMPO as a recyclable catalyst in the Anelli oxidation of alcohols is reported. The catalyst is easily obtained in a one-step reductive amination procedure starting from a commercially available aminopropyl-functionalized silica. Details of the synthesis of the supported catalyst and its analysis by MAS NMR are presented. Various alcohol oxidations according to the Anelli protocol have been carried out and the stability of the applied silica-supported TEMPO has been studied.