de.mpg.escidoc.pubman.appbase.FacesBean
Deutsch
 
Hilfe Wegweiser Impressum Kontakt Einloggen
  DetailsucheBrowse

Datensatz

DATENSATZ AKTIONENEXPORT

Freigegeben

Zeitschriftenartikel

Process Configurations for the production of the 2-methoxy-2,4,4-trimethylpentane : a novel gasoline oxygenate

MPG-Autoren
http://pubman.mpdl.mpg.de/cone/persons/resource/persons86450

Rihko-Struckmann,  Liisa
Process Systems Engineering, Max Planck Institute for Dynamics of Complex Technical Systems, Max Planck Society;

Externe Ressourcen
Es sind keine Externen Ressourcen verfügbar
Volltexte (frei zugänglich)
Es sind keine frei zugänglichen Volltexte verfügbar
Ergänzendes Material (frei zugänglich)
Es sind keine frei zugänglichen Ergänzenden Materialien verfügbar
Zitation

Rihko-Struckmann, L., Karinen, R. S., Krause, A. O. I., Jakobsson, K., & Aittamaa, J. R. (2004). Process Configurations for the production of the 2-methoxy-2,4,4-trimethylpentane: a novel gasoline oxygenate. Chemical Engineering and Processing, 43, 57-65. doi:10.1016/S0255-2701(02)00185-X.


Zitierlink: http://hdl.handle.net/11858/00-001M-0000-0013-9E99-D
Zusammenfassung
A comparison of various process configurations was made for the production of 2-methoxy-2,4,4-trimetylpentane which is a promising gasoline component owing low solubility to water and high octane value. The ether is synthesised by reacting methanol with a mixture of 2,4,4-trimethyl-1-pentene and 2,4,4-trimethyl-2-pentene, which are obtained in a large scalefrom the dimerisation of isobutene. The reaction equilibria were determined experimentally at temperature range 323- 383 K in liquid phase using a commercial cation exchange resin Amberlyst 35 as catalyst. A first order kinetic model was developed and utilised in the process simulations. The production of the ether was found to inefficient in a once throug tubular reactor, because the conversion is stronly limited by the reaction equilibrium. Reactive distillation increases the conversion considerably.