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VLE and LLE data for the system cyclohexane plus cyclohexene plus water plus cycloblexanol

MPS-Authors
http://pubman.mpdl.mpg.de/cone/persons/resource/persons86492

Steyer,  Frank
Process Systems Engineering, Max Planck Institute for Dynamics of Complex Technical Systems, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons86497

Sundmacher,  Kai
Process Systems Engineering, Max Planck Institute for Dynamics of Complex Technical Systems, Max Planck Society;
Otto-von-Guericke-Universität Magdeburg, External Organizations;

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Citation

Steyer, F., & Sundmacher, K. (2004). VLE and LLE data for the system cyclohexane plus cyclohexene plus water plus cycloblexanol. Journal of Chemical and Engineering Data, 49(6), 1675-1681. doi:10.1021/je049902w.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0013-9E3F-8
Abstract
The ternary system cyclohexene + water + cyclohexanol is currently being studied with the aim of carrying out the reaction of cyclohexene and water to cyclohexanol in a reactive distillation column. The challenge this system poses for such a reactive separator lies in the liquid-liquid phase splitting behavior, which adds a third effect in addition to reaction and distillation. Cyclohexane is added as a fourth component into these studies, representing any C₆ inerts. To be able to describe the activities of all four components, measurements were conducted of the liquid-liquid and vapor-liquid equilibria, and appropriate NRTL parameters matching both vapor-liquid and liquid-liquid phase splitting behavior were identified.