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Theoretical Investigations of Steady State Multiplicities in Solid Oxide Fuel Cells

MPG-Autoren
http://pubman.mpdl.mpg.de/cone/persons/resource/persons86397

Mangold,  M.
Process Synthesis and Process Dynamics, Max Planck Institute for Dynamics of Complex Technical Systems, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons86373

Krasnyk,  M.
Process Synthesis and Process Dynamics, Max Planck Institute for Dynamics of Complex Technical Systems, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons86497

Sundmacher,  Kai
Process Systems Engineering, Max Planck Institute for Dynamics of Complex Technical Systems, Max Planck Society;
Otto-von-Guericke-Universität Magdeburg, External Organizations;

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Zitation

Mangold, M., Krasnyk, M., & Sundmacher, K. (2006). Theoretical Investigations of Steady State Multiplicities in Solid Oxide Fuel Cells. Journal of Applied Electrochemistry, 36(3), 265-275. doi:10.1007/s10800-005-9080-0.


Zitierlink: http://hdl.handle.net/11858/00-001M-0000-0013-9A8A-2
Zusammenfassung
The nonlinear steady state behaviour of solid oxide fuel cells (SOFCs) is investigated. It is found that the temperature dependence of the electrolyte's conductivity has a very strong influence on the occurrence of multiple steady states, instabilities and the formation of hot spots. Two correlations from literature for the electrolyte's conductivity are studied in a lumped model and in a 1D spatially distributed model of a SOFC. The cases of galvanostatic operation, potentiostatic operation, and operation under a constant ohmic load are considered. The lumped model possesses a unique steady state under galvanostatic operation and up to three steady states under potentiostatic operation or under constant load. In the distributed model, three steady states may coexist under galvanostatic operation and up to five under potentiostatic operation. © Springer 2005. [accessed 2014 January 9th]