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Solid−Liquid Equilibria of N-Methylephedrine Enantiomers and Their Mixtures in Three Chiral Solvents Distinguished by Chain Length

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http://pubman.mpdl.mpg.de/cone/persons/resource/persons86505

Tulashie,  S. K.
Physical and Chemical Foundations of Process Engineering, Max Planck Institute for Dynamics of Complex Technical Systems, Max Planck Society;
Otto-von-Guericke-Universität Magdeburg, External Organizations;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons86390

Lorenz,  H.
Physical and Chemical Foundations of Process Engineering, Max Planck Institute for Dynamics of Complex Technical Systems, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons86477

Seidel-Morgenstern,  A.
Physical and Chemical Foundations of Process Engineering, Max Planck Institute for Dynamics of Complex Technical Systems, Max Planck Society;
Otto-von-Guericke-Universität Magdeburg, External Organizations;

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Citation

Tulashie, S. K., Lorenz, H., & Seidel-Morgenstern, A. (2010). Solid−Liquid Equilibria of N-Methylephedrine Enantiomers and Their Mixtures in Three Chiral Solvents Distinguished by Chain Length. Journal of Chemical and Engineering Data, 55(12), 5824-5828. doi:10.1021/je1007839.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0013-911C-F
Abstract
Solubility equilibria of the chiral N-methylephedrine species in three chiral solvents, (S)-methyl lactate, (S)-propyl lactate, and (S)-butyl lactate, have systematically been studied. Solubility measurements were performed for enantiomeric compositions ranging from 1:1 mixtures to the pure enantiomer and at temperatures between (273 and 298) K. The influence of increasing chain length of the chiral solvents on solubility has been evaluated. copyright American Chemical Society [accessed November 19th, 2010]