Multicomponent Dosing in Membrane Reactors Including Recycling – Concept and 
Demonstration for the Oxidative Dehydrogenation of Propane

Hamel, C.; Wolff, T.; Pushpavanam, S.; Seidel-Morgenstern, A.

doi:10.1021/ie2001692

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Multicomponent Dosing in Membrane Reactors Including Recycling – Concept and Demonstration for the Oxidative Dehydrogenation of Propane

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Hamel, C.
Physical and Chemical Foundations of Process Engineering, Max Planck Institute for Dynamics of Complex Technical Systems, Max Planck Society;
Otto-von-Guericke-Universität Magdeburg, External Organizations;

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Wolff, T.
Physical and Chemical Foundations of Process Engineering, Max Planck Institute for Dynamics of Complex Technical Systems, Max Planck Society;

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Pushpavanam, S.
Indian Institute of Tech., Dep. of Chemical Engineering, Madras, Chennai, India;
Process Synthesis and Process Dynamics, Max Planck Institute for Dynamics of Complex Technical Systems, Max Planck Society;

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Seidel-Morgenstern, A.
Physical and Chemical Foundations of Process Engineering, Max Planck Institute for Dynamics of Complex Technical Systems, Max Planck Society;
Otto-von-Guericke-Universität Magdeburg, External Organizations;

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引用

Hamel, C., Wolff, T., Pushpavanam, S., & Seidel-Morgenstern, A. (2011). Multicomponent Dosing in Membrane Reactors Including Recycling – Concept and Demonstration for the Oxidative Dehydrogenation of Propane. Industrial and Engineering Chemistry Research, 50(23), 12895-12903. doi:10.1021/ie2001692.

引用: https://hdl.handle.net/11858/00-001M-0000-0013-8E12-F

要旨

The potential of a multi-component distributed reactant dosing via membranes was investigated including an internal reactant recycling for enhancing selectivity and yield in networks of parallel and series reactions. In a preliminary theoretical feasibility study was found, that optimal local concentrations of all reactants involved could be adjusted to improve selectivity and conversion of the desired intermediate product. These results were evaluated in a case study. The oxidative dehydrogenation of propane to the kinetically limited intermediate product propylene was considered using a VO_x/γ-Al₂O₃ catalyst. Kinetic equations and parameters were derived initially. Compared to a single-component dosing of O₂ via membranes, the yield of propylene could be almost trebled by a controlled simultaneous dosing of oxygen and propane including. Copyright © 2011 American Chemical Society [accessed May 27th 2011]