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Journal Article

Stereoselective Intramolecular Cyclopropanation through Catalytic Olefin Activation

MPS-Authors
http://pubman.mpdl.mpg.de/cone/persons/resource/persons58636

Huang,  Xueliang
Research Group Maulide, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons58701

Klimczyk,  Sebastian
Research Group Maulide, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Huang, X., Klimczyk, S., & Veiros, L. F. (2013). Stereoselective Intramolecular Cyclopropanation through Catalytic Olefin Activation. Chemical Science, 4(8), 1105-1110. doi:10.1039/C2SC21914J.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0014-A37A-0
Abstract
A novel stereoselective and convergent catalytic method for the cyclopropanation of electron-neutral and -rich olefins by sulfonium ylides is reported which unusually proceeds through olefin activation rather than by metal carbene formation.