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Abstract

As part of the JGOFS field program, extensive CO₂ partial- pressure measurements were made in the atmosphere and in the surface waters of the equatorial Pacific from 1992 to 1999. For the first time, we are able to determine how processes occurring in the western portion of the equatorial Pacific impact the sea-air fluxes Of CO₂ in the central and eastern regions. These 8 years of data are compared with the decade of the 1980s. Over this period, surface-water pCO(2) data indicate significant seasonal and interannual variations. The largest decreases in fluxes were associated with the 1991-94 and 1997- 98 El Ni (n) over tildeo events. The lower sea-air CO₂ fluxes during these two El Ni (n) over tildeo periods were the result of the combined effects of interconnected large-scale and locally forced physical processes: (1) development of a low- salinity surface cap as part of the formation of the warm pool in the western and central equatorial Pacific, (2) deepening of the thermocline by propagating Kelvin waves in the eastern Pacific, and (3) the weakening of the winds in the eastern half of the basin. These processes serve to reduce pCO(2) values in the central and eastern equatorial Pacific towards near- equilibrium values at the height of the warm phase of ENSO. In the western equatorial Pacific there is a small but significant increase in seawater pCO(2) during strong El Ni (n) over tildeo events (i.e., 1982-83 and 1997-98) and little or no change during weak El Ni (n) over tildeo events (1991-94). The net effect of these interannual variations is a lower-than-normal CO₂ flux to the atmosphere from the equatorial Pacific during El Ni (n) over tildeo. The annual average fluxes indicate that during strong El Ni (n) over tilde os the release to the atmosphere is 0.2-0.4 Pg C yr(-1) compared to 0.8-1.0 Pg C yr-1 during non-El Ni (n) over tildeo years. (C) 2002 Published by Elsevier Science Ltd.