de.mpg.escidoc.pubman.appbase.FacesBean
Deutsch
 
Hilfe Wegweiser Impressum Kontakt Einloggen
  DetailsucheBrowse

Datensatz

DATENSATZ AKTIONENEXPORT

Freigegeben

Zeitschriftenartikel

Incipient chemical bond formation of Xe to a cationic silicon cluster: Vibrational spectroscopy and structure of the Si4Xe+ complex

MPG-Autoren
http://pubman.mpdl.mpg.de/cone/persons/resource/persons21601

Harding,  Daniel J.
Molecular Physics, Fritz Haber Institute, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons21506

Fielicke,  André
Molecular Physics, Fritz Haber Institute, Max Planck Society;

Externe Ressourcen
Es sind keine Externen Ressourcen verfügbar
Volltexte (frei zugänglich)

Si4Xe_CPL.pdf
(beliebiger Volltext), 244KB

Ergänzendes Material (frei zugänglich)
Es sind keine frei zugänglichen Ergänzenden Materialien verfügbar
Zitation

Savoca, M., Langer, J., Harding, D. J., Dopfer, O., & Fielicke, A. (2013). Incipient chemical bond formation of Xe to a cationic silicon cluster: Vibrational spectroscopy and structure of the Si4Xe+ complex. Chemical Physics Letters, 557, 49-52. doi:10.1016/j.cplett.2012.12.020.


Zitierlink: http://hdl.handle.net/11858/00-001M-0000-000E-95EB-2
Zusammenfassung
The size-selective vibrational spectrum of Si4Xe+ in the 240–500 cm-1 range has been recorded using infrared (IR) multiple photon dissociation spectroscopy. Comparison to linear IR absorption spectra of Si4+ and Si4Xe+ calculated using density functional theory including dispersion corrections reveals an important influence of the Xe ligand on the structure of the cluster, involving significant charge transfer and formation of an incipient chemical Si–Xe bond with De = 0.3 eV.