de.mpg.escidoc.pubman.appbase.FacesBean
English
 
Help Guide Disclaimer Contact us Login
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT

Released

Journal Article

Efficient formation and cleavage of disilanes by potassium-graphite. Silylation with silyl metal reagents

MPS-Authors
There are no MPG-Authors available
Locator
There are no locators available
Fulltext (public)
There are no public fulltexts available
Supplementary Material (public)
There is no public supplementary material available
Citation

Fürstner, A., & Weidmann, H. (1988). Efficient formation and cleavage of disilanes by potassium-graphite. Silylation with silyl metal reagents. Journal of Organometallic Chemistry, 354(1), 15-21. doi:10.1016/0022-328X(88)80634-X.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0010-259D-0
Abstract
Potassium-graphite laminate (C8K) very rapidly forms disilanes from chlorosilanes and then rapidly cleaves the disilanes to give silyl potassium reagents which can be converted into potassium silyl cuprates, -manganates, and -vanadates that are useful for nucleophilic substitution and addition reactions.