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Activation of H2O2 by Chiral Confined Brønsted Acids: A Highly Enantioselective Catalytic Sulfoxidation

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Liao,  Saihu
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Čorić,  Ilija
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Wang,  Qinggang
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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List,  Benjamin
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Liao, S., Čorić, I., Wang, Q., & List, B. (2012). Activation of H2O2 by Chiral Confined Brønsted Acids: A Highly Enantioselective Catalytic Sulfoxidation. Journal of the American Chemical Society, 134(26), 10765-10768. doi:10.1021/ja3035637.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0010-2320-7
Abstract
Confined chiral Brønsted acids are shown to catalyze asymmetric oxidations of sulfides to sulfoxides with hydrogen peroxide. The wide generality and high enantioselectivity of the developed method compare even to the best metal-based systems and suggest utility in other asymmetric oxidations.