English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT

Released

Journal Article

Synthesis and Rearrangement Reactions of C-Alkylidene Carbohydrates

MPS-Authors
There are no MPG-Authors in the publication available
External Resource
No external resources are shared
Fulltext (restricted access)
There are currently no full texts shared for your IP range.
Fulltext (public)
There are no public fulltexts stored in PuRe
Supplementary Material (public)
There is no public supplementary material available
Citation

Csuk, R., Fürstner, A., & Weidmann, H. (1986). Synthesis and Rearrangement Reactions of C-Alkylidene Carbohydrates. Journal of Carbohydrate Chemistry, 5(2), 271-285. doi:10.1080/07328308608062966.


Cite as: https://hdl.handle.net/11858/00-001M-0000-000F-F153-B
Abstract
Direct: olefinations on one hand in comparison to eliminations of aldols cf various uloses on the other each proved to be specific as to the sice of unsaturation in the branched-chain products, found to be interconvertible with one exception under a variety of conditions. Although shown to be generally equivalent to its Witcig-counterpart:, the Peterson reagent employed is liable to cause eliminations in the initial olefin. One of the branched-chain products appears to be of unusual molecular rigidity as evidenced by a large 5J coupling.