Branching of Ketosugars by Ethyl Trimethylsilyl-Acetate/Tetra-n-Butylammonium 
Fluoride

Csuk, René; Fürstner, Alois; Weidmann, Hans

doi:10.1080/07328308608082644

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Branching of Ketosugars by Ethyl Trimethylsilyl-Acetate/Tetra-n-Butylammonium Fluoride

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Citation

Csuk, R., Fürstner, A., & Weidmann, H. (1986). Branching of Ketosugars by Ethyl Trimethylsilyl-Acetate/Tetra-n-Butylammonium Fluoride. Journal of Carbohydrate Chemistry, 5(1), 77-82. doi:10.1080/07328308608082644.

Cite as: https://hdl.handle.net/11858/00-001M-0000-000F-F123-8

Abstract

Hexopyranose- and hexofuranose-uloses, on treatment with ethyl trimethylsilylacetate/tetra-n-butylammohium fluoride, form β-hydroxy esters or derivatives thereof instead of their TMS-enol ethers. ²⁹Si NMR studies confirm the proposed mechanism.