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Total Synthesis and Structural Revision of the Piperarborenines: When Photochemistry Meets C-H Activation

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http://pubman.mpdl.mpg.de/cone/persons/resource/persons58809

Maulide,  Nuno
Research Group Maulide, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons58553

Frébault,  Frédéric
Research Group Maulide, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Maulide, N., & Frébault, F. (2012). Total Synthesis and Structural Revision of the Piperarborenines: When Photochemistry Meets C-H Activation. Angewandte Chemie International Edition: a journal of the Gesellschaft Deutscher Chemiker, 51(12), 2815-2817. doi:10.1002/anie.201108592.


Cite as: http://hdl.handle.net/11858/00-001M-0000-000F-F075-7
Abstract
Activate and reiterate: The activation of C(sp3)H bonds is a highly desirable transformation because molecular complexity can be increased at the expense of the most simple and readily available organic linkage. In recent contributions this approach was used for coupling reactions with small all-carbon rings, as exemplified by the sequential CH activation steps in an elegant total synthesis of the piperarborenines (see scheme; DG=directing group).