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Aiding the Self-Assembly of Supramolecular Polyoxometalates under Hydrothermal Conditions To Give Precursors of Complex Functional Oxides

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Sanchez Sanchez,  Maricruz
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Girgsdies,  Frank
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Jastak,  Mateusz
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Kube,  Pierre
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Schlögl,  Robert
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Trunschke,  Annette
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Citation

Sanchez Sanchez, M., Girgsdies, F., Jastak, M., Kube, P., Schlögl, R., & Trunschke, A. (2012). Aiding the Self-Assembly of Supramolecular Polyoxometalates under Hydrothermal Conditions To Give Precursors of Complex Functional Oxides. Angewandte Chemie International Edition, 51(29), 7194-7197. doi:10.1002/anie.201200746.


Cite as: https://hdl.handle.net/11858/00-001M-0000-000F-C6F4-B
Abstract
n situ Raman spectroscopy allows insight into molecular processes under hydrothermal conditions during synthesis of complex nanostructured MoVTeNb oxides (see picture: Nb yellow, Mo blue, V/Mo pale blue, Te red). Based on the knowledge acquired, the synthesis can be more efficiently directed towards the desired product with improved functionality.