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Selective oxidation of cyclooctane to cyclootanone with molecular oxygen in the presence of compressed carbon dioxide

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http://pubman.mpdl.mpg.de/cone/persons/resource/persons59042

Theyssen,  N.
Service Department Theyssen (Technical Labs), Max-Planck-Institut für Kohlenforschung, Max Planck Society;
Service Department Theyssen (Technical Labs), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons58749

Leitner,  W.
Service Department Leitner (Technical Labs), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Theyssen, N., & Leitner, W. (2002). Selective oxidation of cyclooctane to cyclootanone with molecular oxygen in the presence of compressed carbon dioxide. Chemical Communications, (5), 410-411. doi:10.1039/B111212K.


Cite as: http://hdl.handle.net/11858/00-001M-0000-000F-9A61-8
Abstract
The oxidation of cyclooctane (1) to cyclooctanone (3) with molecular oxygen and acetaldehyde (2) as a co-reductant occurs efficiently in the presence of compressed CO2. Up to 20% yields of 3 are obtained under optimised multiphase conditions.