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Direct Zn-diamine promoted reduction of C=O and C=N bonds by polymethylhydrosiloxane in methanol

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Lehmann,  Christian W.
Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Bette, V., Mortreux, A., Lehmann, C. W., & Carpentier, J.-F. (2003). Direct Zn-diamine promoted reduction of C=O and C=N bonds by polymethylhydrosiloxane in methanol. Chemical Communications, 2003(3), 332-333. doi:10.1039/B210144K.


Cite as: https://hdl.handle.net/11858/00-001M-0000-000F-98EB-6
Abstract
Ketones and imines are chemoselectively reduced at room temperature in methanol to the corresponding alcohols and amines in high yields in a one-step procedure using polymethylhydrosiloxane (PMHS) and a simple zinc–diamine catalyst.