Isolation of a Novel Singly Oxo-bridged Low-spin Fe(II) Dimeric Complex: 
Synthesis, Crystal Structure, and Spectroscopic Study

Saha, Manas Kumar; Dey, Dilip Kumar; Choudhury, Chirantan Roy; Dey, Subrata Kumar; Mitra, Samiran; Lehmann, Christian W.

doi:10.1246/cl.2003.1136

Item

ITEM ACTIONSEXPORT

Add to Basket

Local TagsRelease HistoryDetailsSummary

Released

Journal Article

Isolation of a Novel Singly Oxo-bridged Low-spin Fe(II) Dimeric Complex: Synthesis, Crystal Structure, and Spectroscopic Study

MPS-Authors

/persons/resource/persons58744

Lehmann, Christian W.
Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

External Resource

No external resources are shared

Fulltext (restricted access)

There are currently no full texts shared for your IP range.

Fulltext (public)

There are no public fulltexts stored in PuRe

Supplementary Material (public)

There is no public supplementary material available

Citation

Saha, M. K., Dey, D. K., Choudhury, C. R., Dey, S. K., Mitra, S., & Lehmann, C. W. (2003). Isolation of a Novel Singly Oxo-bridged Low-spin Fe(II) Dimeric Complex: Synthesis, Crystal Structure, and Spectroscopic Study. Chemistry Letters, 32(12), 1136-1137. doi:10.1246/cl.2003.1136.

Cite as: https://hdl.handle.net/11858/00-001M-0000-000F-97EF-4

Abstract

Redox reaction between [(phen)₄Fe₂(Cl)₂(μ-O)]Cl₂·4.5H₂O (phen = 1,10-phenanthroline) and Mn(OH)₂·xH₂O in water methanol solution at refluxing temperature under inert atmosphere gives a novel low-spin iron(II)–oxo complex [(phen)₄Fe₂(Cl)₂(μ-O)]·4H₂O (1) which has been characterised by IR, Mössbauer, electrochemical and magnetic studies. The crystal structure shows that complex 1 is a dinuclear single oxo-bridged Fe(II) species with distorted octahedral geometry.