Highly Syndiospecific Polymerization of Styrene Catalyzed by Allyl Lanthanide 
Complexes

Kirillov, Evgueni; Lehmann, Christian W.; Razavi, Abbas; Carpentier, Jean-François

doi:10.1021/ja0455695

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Highly Syndiospecific Polymerization of Styrene Catalyzed by Allyl Lanthanide Complexes

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Lehmann, Christian W.
Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Kirillov, E., Lehmann, C. W., Razavi, A., & Carpentier, J.-F. (2004). Highly Syndiospecific Polymerization of Styrene Catalyzed by Allyl Lanthanide Complexes. Journal of the American Chemical Society, 126(39), 12240-12241. doi:10.1021/ja0455695.

Cite as: https://hdl.handle.net/11858/00-001M-0000-000F-976B-E

Abstract

Allylic complexes of lanthanides bearing a fluorenyl-based ligand are active single-component catalysts for the polymerization of styrene, giving highly syndiotactic polymers (rrrr > 99%) with low to high molecular weight (M_n = 8000−135 000) and narrow polydispersities (M_w/M_n = 1.25−2.1).